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Facile generation of highly durable thiol-functionalized polyhedral oligomeric silsesquioxane based superhydrophobic

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1247-1258 doi: 10.1007/s11705-021-2124-0

Abstract: durable superhydrophobic/superoleophilic melamine foam was fabricated by a facile and rapid one-step thiol-eneFirst, 1H, 1H, 2H-perfluoro-1-hexene reacted with thiol-functionalized polyhedral oligomeric silsesquioxanevia the thiol-ene click chemistry to obtain a fluorinated thiol-functionalized polyhedral oligomericsilsesquioxane solution.

Keywords： superhydrophobic melamine foam     thiol-functionalized polyhedral oligomeric silsesquioxane     durable     oil    

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Cube-octameric silsesquioxane (POSS)-capped magnetic iron oxide nanoparticles for the efficient removal

Ali Akbari, Nasser Arsalani, Bagher Eftekhari-Sis, Mojtaba Amini, Gholamreza Gohari, Esmaiel Jabbari

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 563-573 doi: 10.1007/s11705-018-1784-x

Abstract: Octavinyl polyhedral oligomeric silsesquioxane (POSS) was polymerized on the surface of Fe O nanoparticles(NPs) and then the NPs were functionalized with carboxylic acid groups using thiol-ene click reactions

Keywords： nanomagnetic POSS     surface polymerization     thiol-ene reaction     adsorbent     water treatment    

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Polyhedral linkages obtained as assemblies of planar link groups

GÖkhan KİPER, Eres SÖYLEMEZ

Frontiers of Mechanical Engineering 2013, Volume 8, Issue 1,   Pages 3-9 doi: 10.1007/s11465-013-0363-6

Abstract:

The study aims to devise means of obtaining polyhedral linkages for homothetic deployment of polyhedralshapes by embedding planar link groups in faces of the polyhedral shape of interest.The questions of which polyhedral shapes may be suitable for such a purpose and what are the compatibilityHomohedral and tangential polyhedral shapes are found to be suitable for the task and some examples of

Keywords： polyhedral linkages     homothety     homohedra     tangential polyhedra    

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Continuous amino-functionalized University of Oslo 66 membranes as efficacious polysulfide barriers for

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 2,   Pages 194-205 doi: 10.1007/s11705-022-2206-7

Abstract: Herein, continuous amino-functionalized University of Oslo 66 membranes supported on carbon nanotube

Keywords： lithium−sulfur batteries     amino-functionalized University of Oslo 66 membrane     polysulfide     interlayer    

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Improved “cure on demand” of aromatic bismaleimide with thiol triggered by retro-Diels-Alder reaction

Vincent Froidevaux, Mélanie Decostanzi, Abdelatif Manseri, Sylvain Caillol, Bernard Boutevin, Rémi Auvergne

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 2,   Pages 330-339 doi: 10.1007/s11705-020-1929-6

Abstract: The retro-DA reactions of both aromatic and aliphatic DA adducts in presence of thiol molecules were

Keywords： thiol-ene polymerization     self-curing on demand     thia-michael addition     Diels-Alder     maleimide    

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detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework with amido functionalized

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 12, doi: 10.1007/s11783-022-1594-8

Abstract:

● A novel Al-MOF was successfully synthesized by a facile solvothermal method.

Keywords： Fluorescence     Metal-organic framework     Phosphate     Detection     Al-MOF    

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removal of total oxidizable carbon, phosphate and various metallic ions from HO solution with amino-functionalized

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 470-482 doi: 10.1007/s11705-022-2231-6

Abstract: Amino-functionalized zirconia was synthesized by the co-condensation method using zirconium butanol andresults of Fourier transform infrared (FTIR) and Zeta potential showed that the content of N in amino-functionalizedstudies conducted using simulated solutions showed that the adsorption process of phosphate on amino-functionalized

Keywords： adsorption     zirconia     total oxidizable carbon     phosphate     metallic ions     hydrogen peroxide    

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Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1537-1549 doi: 10.1007/s11705-021-2094-2

Abstract: Human health is deteriorating due to the effluent containing heavy metal ions and organic dyes. Hence, photoreduction of Cr(VI) to Cr(III) and degradation of rhodamine B (RhB) using a novel photocatalyst is particularly important. In this work, h-BN/NiS2/NiS composites were prepared via a simple solvothermal method and a double Z-scheme heterojunction was constructed for efficiently removing RhB and Cr(VI). The 7 wt-% h-BN/NiS2/NiS composites were characterized via a larger specific surface area (15.12 m2·g–1), stronger light absorption capacity, excellent chemical stability, and high yield of electrons and holes. The experimental result indicated that the photoreduction efficiency of the 7 wt-% h-BN/NiS2/NiS photocatalyst achieved 98.5% for Cr(VI) after 120 min, which was about 3 times higher than that of NiS2/NiS (34%). However, the removal rate of RhB by the 7 wt-% h-BN/NiS2/NiS photocatalyst reached 80%. This is due to the double Z-scheme heterojunction formed between NiS2/NiS and h-BN, which improved the charge separation efficiency and transmission efficiency. Besides, the influence of diverse photogenerated electron and hole scavengers upon the photoreduction of Cr(VI) was studied, the results indicated that graphene-like h-BN promoted transportation of photoinduced charges on the surface of the h-BN/NiS2/NiS photocatalyst via the interfacial effects.

Keywords： graphene-like h-BN     h-BN/NiS2/NiS composites     photocatalysis     Cr(VI) reduction     degradation of RhB    

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Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1198-1210 doi: 10.1007/s11705-021-2133-z

Abstract: Sulfonic acid functionalized mesoporous silica based solid acid catalysts with different morphology wereThe sulfonic acid functionalized mesoporous silica catalysts of spherical shape and the cube shape were

Keywords： solid acid catalyst     mesoporous silica     sulfonic acid     biodiesel     esterification     oleic acid    

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-Cyclodextrin functionalized graphene oxide: an efficient and recyclable adsorbent for the removal of

Shanshan WANG, Yang LI, Xiaobin FAN, Fengbao ZHANG, Guoliang ZHANG

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 1,   Pages 77-83 doi: 10.1007/s11705-014-1450-x

Abstract: A novel method for the preparation of -cyclodextrin grafted graphene oxide (GO- -CD) has been developed. The GO- -CD was characterized by Fourier transform infrared spectroscopy, C NMR spectroscopy, Raman spectroscopy and thermogravimetric analysis. The ability of GO- -CD to remove fuchsin acid from solution was also studied. The GO- -CD had an excellent adsorption capacity for fuchsin acid and could be recycled and reused. The adsorption capacities of GO- -CD for other dye pollutants such as methyl orange and methylene blue were also investigated. The absorption capacities for the three dyes are in the order: fuchsin acid>methylene blue>methyl orange.

Keywords： graphene oxide     β-cyclodextrin     adsorption capacity     recycle    

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2-Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 389-395 doi: 10.1007/s11705-016-1575-1

Abstract: A palladium catalyst supported on 2-aminopyridine functionalized cellulose was synthesized and fully

Keywords： cellulose-supported     2-aminopyridine     palladium nanoparticles     ecofriendly catalyst     Suzuki cross-coupling reaction    

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Separation/degradation behavior and mechanism for cationic/anionic dyes by Ag-functionalized FeO-PDA

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 11, doi: 10.1007/s11783-022-1572-1

Abstract:

● PDA-Fe3O4-Ag was made by hydrothermal and oxidation self-polymerization method.

Keywords： PDA     Fe3O4     Magnetic adsorbent     Cationic dyes     Anionic dyes    

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Synthesis and properties of novel organogelators functionalized with 5-iodo-1,2,3-triazole and azobenzene

Ziyan Li,Yaodong Huang,Dongli Fan,Huimin Li,Shuxue Liu,Luyuan Wang

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 4,   Pages 552-561 doi: 10.1007/s11705-016-1589-8

Abstract: Two series of 5-iodo-1,2,3-triazole derivatives containing azobenzene group(s) were synthesized and their gelling properties were tested. Those containing two azobenzene groups ( series) have better gelation performance than those containing one azobenzene group ( series). The microstructure of organogels and the driving force of gelation were investigated by scanning electron microscopy and H NMR, respectively. It was found that π-π stacking, van der Waals interaction, and dipole-dipole interaction were the main forces of gelation. All the tested organogels are photoresponsive and those from series are smarter than that from series. Henry - diagrams of compounds , , and were constructed on the basis of their gelation performance and the Hansen solubility parameters of related solvents. The constructed Henry - diagrams can be used to estimate the behavior of three compounds in any untested solvent.

Keywords： iodo triazole     azobenzene     photoresponsive organogel     gelator-solvent effect    

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Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 408-419 doi: 10.1007/s11705-021-2054-x

Abstract: activated carbon as a nanofiller, this study synthesized a novel environment-friendly polyethylenimine-functionalized

Keywords： polyethylenimine     carboxylated chitosan     activated charcoal     uranyl ion     adsorption    

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Tailoring Anti-Impact Properties of Ultra-High Performance Concrete by Incorporating Functionalized Carbon Article

Jialiang Wang,Sufen Dong,Sze Dai Pang,Xun Yu,Baoguo Han,Jinping Ou

Engineering 2022, Volume 18, Issue 11,   Pages 232-245 doi: 10.1016/j.eng.2021.04.030

Abstract: Unlike ordinary CNTs, functionalized CNTs with carboxyl or hydroxyl groups can break the Si–O&ndashFurthermore, functionalized CNTs, particularly carboxyl-functionalized CNTs, control the crystallizationMoreover, the functionalized CNTs further decrease the attraction of the negatively charged silicateImpact performance of UHPC containing a small amount of carboxyl-functionalized CNTs (especially theshort ones) is generally better than that of UHPC containing hydroxyl-functionalized and ordinary CNTs

Keywords： Functionalized carbon nanotubes     Concrete     Impact properties     Reinforcing mechanisms    

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Title Author Date Type Operation

Facile generation of highly durable thiol-functionalized polyhedral oligomeric silsesquioxane based superhydrophobic

Journal Article

Cube-octameric silsesquioxane (POSS)-capped magnetic iron oxide nanoparticles for the efficient removal

Ali Akbari, Nasser Arsalani, Bagher Eftekhari-Sis, Mojtaba Amini, Gholamreza Gohari, Esmaiel Jabbari

Journal Article

Polyhedral linkages obtained as assemblies of planar link groups

GÖkhan KİPER, Eres SÖYLEMEZ

Journal Article

Continuous amino-functionalized University of Oslo 66 membranes as efficacious polysulfide barriers for

Journal Article

Improved “cure on demand” of aromatic bismaleimide with thiol triggered by retro-Diels-Alder reaction

Vincent Froidevaux, Mélanie Decostanzi, Abdelatif Manseri, Sylvain Caillol, Bernard Boutevin, Rémi Auvergne

Journal Article

detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework with amido functionalized

Journal Article

removal of total oxidizable carbon, phosphate and various metallic ions from HO solution with amino-functionalized

Journal Article

Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

Journal Article

Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Journal Article

-Cyclodextrin functionalized graphene oxide: an efficient and recyclable adsorbent for the removal of

Shanshan WANG, Yang LI, Xiaobin FAN, Fengbao ZHANG, Guoliang ZHANG

Journal Article

2-Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Journal Article

Separation/degradation behavior and mechanism for cationic/anionic dyes by Ag-functionalized FeO-PDA

Journal Article

Synthesis and properties of novel organogelators functionalized with 5-iodo-1,2,3-triazole and azobenzene

Ziyan Li,Yaodong Huang,Dongli Fan,Huimin Li,Shuxue Liu,Luyuan Wang

Journal Article

Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

Journal Article

Tailoring Anti-Impact Properties of Ultra-High Performance Concrete by Incorporating Functionalized Carbon

Jialiang Wang,Sufen Dong,Sze Dai Pang,Xun Yu,Baoguo Han,Jinping Ou

Journal Article